Ferric Nitrate – Iron(Iii) Nitrate

ACC# 00631

Section 1 – Chemical Product and Company Identification

MSDS Name:Iron(III) nitrate nonahydrate, reagent ACSCatalog Numbers:AC423710000, AC423710030, AC423710050, AC423715000Synonyms:Nitric Acid Iron (3+) Salt Nonahydrate.

Đang xem: Ferric nitrate

Company Identification: Acros Organics N.V. One Reagent Lane Fair Lawn, NJ 07410For information in North America, call:800-ACROS-01For emergencies in the US, call CHEMTREC:800-424-9300

Section 3 – Hazards Identification

EMERGENCY OVERVIEW

Appearance: off-white or light purple crystals (moist). Hygroscopic (absorbs moisture from the air). May cause methemoglobinemia. May cause eye and skin irritation. May cause respiratory and digestive tract irritation.Danger!Strong oxidizer. Contact with other material may cause a fire.Target Organs:Blood, kidneys, heart, central nervous system, liver.Potential Health EffectsEye:May cause eye irritation.Skin:May cause skin irritation.Ingestion:May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, and death.Inhalation:May cause respiratory tract irritation. May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, tachycardia, dyspnea (labored breathing), and death. Methemoglobinemia is characterized by dizziness, drowsiness, headache, shortness of breath, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), rapid heart rate and chocolate-brown blood.Chronic:May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis (bluish skin due to deficient oxygenation of blood), rapid heart rate, unconsciousness and possible death.

Section 4 – First Aid Measures

Eyes:Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.Skin:Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.Ingestion:If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.Inhalation:Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.Notes to Physician:Treat symptomatically and supportively.Antidote:The use of Deferoxamine as a chelating agent should be determined only by qualified medical personnel.

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Section 5 – Fire Fighting Measures

General Information:As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with combustible materials may cause a fire. Use water spray to keep fire-exposed containers cool. Use water with caution and in flooding amounts.Extinguishing Media:Use water only! Contact professional fire-fighters immediately. Do NOT use dry chemicals, CO2, Halon or foams.Flash Point:Not available.Autoignition Temperature:Not available.Explosion Limits, Lower:Not available.Upper:Not available.NFPA Rating:(estimated) Health: 1; Flammability: 0; Instability: 0; Special Hazard: OX

Section 6 – Accidental Release Measures

General Information:Use proper personal protective equipment as indicated in Section 8.Spills/Leaks:Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation. In case of spill, sweep up solid or absorb liquid with inert material, then place into a biohazard container. Wear protective equipment.

Section 7 – Handling and Storage

Handling:Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid contact with clothing and other combustible materials. Avoid ingestion and inhalation.Storage:Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 – Exposure Controls, Personal Protection

Engineering Controls:Use adequate ventilation to keep airborne concentrations low.Exposure Limits

Chemical Name ACGIH NIOSH OSHA – Final PELs
Iron(III) nitrate nonahydrate none listed none listed none listed
Ferric nitrate anhydrous none listed none listed none listed
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OSHA Vacated PELs:Iron(III) nitrate nonahydrate: No OSHA Vacated PELs are listed for this chemical. Ferric nitrate anhydrous: No OSHA Vacated PELs are listed for this chemical.Personal Protective EquipmentEyes:Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA”s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.Skin:Wear appropriate protective gloves to prevent skin exposure.

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Clothing:Wear appropriate protective clothing to prevent skin exposure.Respirators:Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 – Physical and Chemical Properties

Physical State:Crystals (moist)Appearance:off-white or light purpleOdor:None reported.pH:Not available.Vapor Pressure:Negligible.Vapor Density:Not available.Evaporation Rate:Negligible.Viscosity:Not available.Boiling Point:Not available.Freezing/Melting Point:47.2 deg CDecomposition Temperature:Not available.Solubility:Soluble.Specific Gravity/Density:Not available.Molecular Formula:FeN3O9.9H2OMolecular Weight:404.00

Section 10 – Stability and Reactivity

Chemical Stability:Stable. However, may decompose if heated. Stable. May discolor on exposure to light.Conditions to Avoid:Incompatible materials, light, ignition sources, dust generation, combustible materials.Incompatibilities with Other Materials:Strong oxidizing agents.Hazardous Decomposition Products:Nitrogen oxides.Hazardous Polymerization:Has not been reported.

Section 11 – Toxicological Information

RTECS#:CAS#7782-61-8: NO7175000CAS#10421-48-4: QU8915000LD50/LC50:CAS# 7782-61-8:Oral, rat: LD50 = 3250 mg/kg;CAS# 10421-48-4:Carcinogenicity:CAS# 7782-61-8: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 10421-48-4: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.Epidemiology:No data available.Teratogenicity:No data available.Reproductive Effects:No data available.Neurotoxicity:No data available.Mutagenicity:No data available.Other Studies:No data available.

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Section 12 – Ecological Information

No information available.

Section 13 – Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.RCRA P-Series:None listed.RCRA U-Series:None listed.

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Section 14 – Transport Information

US DOT IATA RID/ADR IMO Canada TDG
Shipping Name: FERRIC NITRATE No information available.
Hazard Class: 5.1
UN Number: UN1466
Packing Group: III

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